Adsorption Equilibrium, Physicochemical Parameters and Colour Deactivation Effects of Activated Carbon for Dye for Waste Water Treatment

Alhassan M(Department of Chemistry, Sokoto State University, Sokoto, Nigeria)
Muhammad Sani Aleiro(Department of Chemistry, Kebbi State University of Science and Technology, Aleiro Kebbi State, Nigeria)
Umar A.U(Department of Chemistry, Sokoto State University, Sokoto, Nigeria)

Article ID: 345

Abstract


Effluents from dye and dyeing industries constitute serious environmental threat and attracting serious attention. Activated carbon prepared from guinea corn husk and maize cobs waste materials was used as a precursor to prepare activated carbon. Variable ratios of the constituent ashes ( 1:1, 1:3 and 3:1) were prepared. The husk and cobs were ashed in a murfle furnace at 400-500oC for 2.5 h. Acid activation was carried out   by washing with HCl (1M) after which it was characterized using XRF which revealed (in variable proportions) the presence of SiO2, Al2O3 and Fe2O3 as dominant oxides in the ashes. Waste water decolourization efficiency of the adsorbents was tested using dye waste water at same contact time using variable absorbent dosage. Higher moisture (96.80±0.56), Ash (12.90±0.35), pH (6.3±0.17), Conductivity (208±1.34) and Bulk density (12.27±0.61) were obtained for guinea corn husk. The best clearity was obtained after batch adsorption experiments at 1:1 which gave the highest adsorption at equilibrium (Qe) of 28.55 compared to 12.750 and 10.900 obtained for 1;3 and 3:1 respectively.

Keywords


Adsorption equilibrium, Dye waste water, Activated carbon, Decolourization

Full Text:

PDF

References


Bansode, R. R., Lorso, J. N., Marshal, W. E., Rao, R. M. and Portier, J. (2002). Adsorption of metal ions by pecan shell granular activated carbon, Bioresource Technol.,89:p 115 – 119.

Garg, V., Amita, M., Kumar R., Gupta, R (2004). Basic dye (methylene blue) removal from simulated waste water by adsorption using Indian rosewood sawdust. Dye and Pigment. 63(1): p243-250.

Malik, P.K(2004) “Dye removal from wastewater using activated carbon developed from sawdust: adsorption equilibrium and kinetics,”Journal of Hazardous Materials., Volume 113, Issues 1–3, 10,p 81–88

JyotsnaGoel, Krishna Kadirvelu ChitraRajagopal, Vinod Kumar Garg,( 2005)“Removal of lead(II) by adsorption using treatedgranular activated carbon: Batch and column studies”,Journal of Hazardous Materials.,Volume 125, Issues 1–3, 17, p211–220

Bansal, R. P. and Goyal, M. (2005). Activated Carbon Adsorption, CRC Press, Taylor & Francis Group, 6000 Broken Sound Parkway N.W, Suite 300 Boca Raton, FL, USA.

Crini G, badot, PM (2008) Progres in Polymer Science 33 399

Tadda , M.A. Ahsan, A , Shitu. A, ElSergany. M, Arunkumar, T. Bipin. J. Abdur Razzaque M. Nik Daud. N (2017). A Review on Activated Carbon: Process, Application and Prospects. Journal of Advanced Civil Engineering Practice and Research. 2(1):7-13,

Labanda J, sabete, J Liorens, J (2009) journal of membrane science 340 234

Lenzy GG, Evangelista, RF, Duarte, ER, Colpini, LSM, Fornari AC, Neto RM, Jorge, LMM, and Santos OAA (2016) desalination and water treatment 57(30) 14132

Shi, B, Li B Wang D Feng H and Tang H (2007) journal of hazardous materials 143 567

Akbari A, Remigy JC, and Aptel P (2002) Chemical Engineeering Processs 41 601

Pia AB, Roca, JAM, Miranda MIA, Clar AI, and Clar MII (2003) Desalination 157 73

Han R, Zhang J, Han P Wang y, Zhao Z and tang M (2009) Chemical engineering Journal 145 496

Shen, Y fan, CC, wei YZ, Du J, Zhu, HB and Zhao Y (2012) Dalton Trans 45 10909.

Lazim, ZM, Mzuin E, hadibarata T and Yusop Z (2015) Journal of Teknogi 74(11) 129

Mittal, A, Jain, R, Mittal J, Varshey S and Sikarwar S (2010) International Journal of Environmental Pollution 43 308

Ngah, WS, Teong LC, and hanafiah, MAKM (2011) carbohydrate Polymers 83 1446

Mahmoodi NM, Arami M and Gharanjig K (2013) Journal Of Environmental And Chemical Engineering 1 406

Kiakhani, MS, Arami, M and gharanjig, K (2013) Journal Of Environmental and Chemical Engineering 1 406

Aziz, H.A., Aliaz, S., Adian, M.N., faridah, Assari, A.H. and Zahari, M.S. (2007) Color removal from landfill leachate by coagulation and Flocculation processes. Bioresource Technology. 98 218-220

Buah. W. MacCarthy, J. Ndur, S.(2016). Conversion of Corn Cobs Waste into Activated Carbons for Adsorption of Heavy Metals from Minerals Processing Wastewater. International Journal of Environmental Protection and Policy. 2330-7536

Galvan-Ruiz, M., Hernandez, J., Banos, L., Noriega-Mntes, J. and Rodriguez-Garcia, M.E (2019). Chaarcterization of Calcium Carbonate, Calcium Oxide and Calcium Hydroxide as Starting Point to the Improvement of Lime for Their Use in Construction. American Society of Civil Engineers (ASCE) 1-20 available online at https://www.researchgate.net/publication/232815496

Kaghazchi T, Madadi M, Yeganeh, M. Soleimani,(2006) in proc. Of CHISA (Ed: Jan Novosad), Czech Society Chemical Engineers, Prague, Czech Republic,

Odebunmi, E., Okeola, F (2001). Preparation and characterization of activatd carbon from waste material. Journal chemical society of Nigeria 26(2): 49-155.

Itodo, U.A (2010); Comparative Studies on the preparation, Adsorption and Evaluation of Activated carbon from selected Animals and agricultural wastes. a Ph.D thesis UDUS

Omomnhenle, S., Ofomaja, A., Okiemen, F (2006) sorption of methylene blue by unmodified and modified citric acid saw dust. Journal chemical society of Nigeria. 390 (1 and 2): p161-164.

Zahangir, A., suleyman A. and Noraini, K (2008) production of Activated carbon from oil palm empty fruit Bunch for Zn Removal. Bul. Conference proceedings 12th int’l water Tech conf. IWTC12 Egypt. P373-383.

Gimba, C., Ocholi, O., Nok, A (2004). Preparation of activated carbon from agricultural coastes ii. cyanide binding with activated carbon matrix from groundnut shell. nig journal of scientific research. 4 (2); p106-110.

Rahman, A., Saad, B., Shaidan, S. and Rizal, S. (2002). Adsorption characteristics of malachite Green on ctivated Carbon Dervied from Rice Husks produced by Chemical Thermal process. Bioresearches Technology, 90(14): p1578-1583

Umar, K. J., Alhassan, M. Ahmad, T. I., Zauro, S. A., Sani, N. A., Lawal, A. M. & Hassan, L. G.(2012). The Proximate, Mineral And Fatty Acids Profile Of White Grubs (Scarabidae) African Journal of Natural Sciences 2012, 15, 7 - 11

Yoshiyuki, S.,. Yutaka, K. (2005) paralysis of plant, animal and Human waste; physical chemical charctristics of the pyrolytic product. Bioresoruce Technology 90(3); p241-247

Alhassan, M., Faruq, U.Z. and Galadima, A. (2019). Mixed-Metal Oxide Catalyst for Liquid Phase Benzene Alkylation. Earthline Journal of Chemical SciencesISSN (Online): 2581-9003 Volume 2, Number 2, 2019, Pages 217-234 https://doi.org/10.34198/ejcs.2219.217234

Odewumi, S.C., Adekeye, J.I.D. and Ojo, O.J. (2012) Petrogenesis and Geotectonic settings of the Granitic rocks of Idefin-Osi-Eruku Area, South western Nigeria Using trace Elements and Rare Earth Element Geochemistry. African jurnal of Natural Sciences 15, 39-51

Zhang, B. , Ji, Y., Wang, Z., Liu, Y., Sun, H., Yang, W. and Wu, P. (2012) Liquid-phase alkylation of benzene with ethylene over postsynthesized MCM-56 analogues, Applied Catalysis A:General 443-444; 103-110. https://doi.org/10.1016/j.apcata.2012.07.028




DOI: http://dx.doi.org/10.36956/rwae.v2i1.345

Refbacks

  • There are currently no refbacks.


Copyright © 2021 The author(s)

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

About Us

Nan Yang Academy of Sciences Pte Ltd (NASS) is located in Singapore. The NASS is to promote a platform for the exchange academic achievements by gathering global scientific institutes, experts and scholars in various fields.

Contact Us

Add.: 12 Eu Tong Sen Street, #07-169, Singapore 059819
Tel.: +65 65881289
Email: contact@nassg.org